Zhang, Di and Shao, Yachuan and Wang, Jian and Li, Zhaojin and Wang, Qiujun and Sun, Huilan and Sun, Qujiang and Wang, Bo (2024) High-stability of heterostructured Bi2S3/VS4/rGO anode enabled by electrolyte optimization for fast-charging sodium-ion batteries. Small Structures, 5 (1). ISSN 2688-4062, DOI https://doi.org/10.1002/sstr.202300217.
Full text not available from this repository.Abstract
Sodium-ion batteries are attracting great attention as an alternative to lithium-ion batteries due to the lower cost and better sustainability of sodium. Although the metal sulfide-based anodes demonstrate much higher theoretical capacity than the hard carbon anodes, the severe capacity degradation and inferior rate capability caused by poor electrical conductivity and sluggish kinetics hinder their applications. Herein, a novel bimetallic sulfide-based anode wrapped by reduced graphene oxide (i.e., Bi2S3/VS4/rGO) is presented, in which the heterointerfaces between Bi2S3 and VS4 are well distributed among the composite, leading to the promoted charge transfer and the improved Na+ transport kinetics. Combined with electrolyte optimization, the Bi2S3/VS4/rGO demonstrates excellent electrochemical performance, including excellent rate capabilities over 10 A g−1, and a long lifespan over 1000 cycles. This work indicates the significance of the synergistic effect of structure regulation and electrolyte optimization for achieving fast-charging performance. © 2023 The Authors. Small Structures published by Wiley-VCH GmbH.
| Item Type: | Article |
|---|---|
| Funders: | Science Foundation of University of Hebei Province [Grant no. BJ2020053], National Natural Science Foundation of China [Grant no.22008053, 52002111], Natural Science Foundation of Hebei Province [Grant no.B2021208061, B2022208006], Hebei Provincial Key Research Projects [Grant no.20310601D, 205A4401D] |
| Uncontrolled Keywords: | Anodes; Electrolytes; Heterostructures; Metal sulfides; Sodium-ion batteries |
| Subjects: | Q Science > Q Science (General) Q Science > QC Physics |
| Divisions: | Faculty of Science > Department of Physics |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 16 Apr 2024 03:52 |
| Last Modified: | 16 Apr 2024 03:52 |
| URI: | http://eprints.um.edu.my/id/eprint/44992 |
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