Aziz, Shujahadeen B. and Abdulwahidc, Rebar T. and Mohammed, Sewara J. and Aziz, Dara M. and Hamsan, Muhamad H. and Halim, Norhana Abdul and Al-Saeedi, Sameerah I. and Karim, Wrya O. and Woo, Haw Jiunn and Kadir, Mohd F. Z. (2024) Clean energy storage device derived from biopolymers with moderate charge-discharge cycles: Structural and electrochemical properties. Journal of Industrial and Engineering Chemistry, 130. pp. 673-687. ISSN 1226-086X, DOI https://doi.org/10.1016/j.jiec.2023.11.044.
Full text not available from this repository.Abstract
This work explores a green biopolymer (GBP) energy storage system to address the growing problem of microplastics that can harm our health. A GBP was made using solution casting with chitosan (CHN) and starch from potato (SPC) as the polymer hosts. Sodium thiocyanate (NaSCN) as Na+ cation provider and glycerol as an environmentally friendly plasticizer were mixed with CHN:SPC host polymers to prepare GBP electrolytes. The electrochemical impedance spectroscopy (EIS) results confirm the boost in DC conductivity. From the AC conductivity spectra, regions ascribing to EP and DC contributions are demonstrated. X-ray diffraction (XRD) and FTIR characterization provide evidence of salt dissociation and amorphous phase improvement. The determination of the ion fraction was achieved by means of TNM. The electrochemical stability of the conducting film was observed to be maintained up to 2.75 V. Cyclic voltammetry (CV), revealing no sign of charge transfer occurring through Faradaic processes at the interface between the electrode and electrolyte. The galvanostatic charge-discharge (GCD) plot displayed a triangular pattern, indicating a low voltage drop and a notable specific capacitance of 70 F/g. Moreover, the EDLC (electrical double-layer capacitor) exhibited an average power density of 1120 W/kg and an energy density of 9.11 Wh/kg.
| Item Type: | Article |
|---|---|
| Funders: | Princess Nourah bint Abdulrahman University [PNURSP2023R58] |
| Uncontrolled Keywords: | Green biopolymer electrolyte; Non-toxic plasticizer; XRD & FTIR study; Electrochemical studies |
| Subjects: | Q Science > QD Chemistry T Technology > TD Environmental technology. Sanitary engineering T Technology > TP Chemical technology |
| Divisions: | Faculty of Science > Department of Physics |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 25 Jun 2024 07:06 |
| Last Modified: | 25 Jun 2024 07:06 |
| URI: | http://eprints.um.edu.my/id/eprint/44231 |
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