Rashid, Muhammad Usman and Wan Daud, Wan Mohd Ashri and Mohidem, Nur Atikah and Mohamad, Mardawani and Akhtar, Javaid and Azam, Mudassar and Miran, Waheed (2022) Methane dry reforming with CO2 over ceria supported Ni catalyst prepared by reverse microemulsion synthesis. Fuel, 317. ISSN 0016-2361, DOI https://doi.org/10.1016/j.fuel.2022.123433.
Full text not available from this repository.Abstract
Reverse microemulsion synthesis route was employed for the preparation of Ni/CeO 2 catalysts with the aim of their application in dry reforming of methane. The catalytic activity and stability of the prepared catalysts was investigated in the temperature range of 550-800 degrees C with the ratio of CH4/CO2 = 1 and at high gas hourly space velocity (GHSV) of reactants (1.2 x 10(5) ml h(-1) g(-1)). In the prepared series of catalysts (20% Ni/CeO2, 40% Ni/CeO2, 80%Ni/CeO2); 40% Ni/CeO2(NC2) exhibited higher catalytic activity and better stability compared to 20% Ni/CeO2 (NCl) and 80% Ni/CeO2 (NC3). Moreover, results indicated that NC2 was found to be stable catalyst for both gas yield and H-2/CO ratio. This study indicated that proper balance between Ni metal and CeO2 content played a critical role in the achievement of better catalyst performance and in the decrease of carbon deposition. The characterization of fresh and spent catalysts was done by BET, XRD, TPR-H-2, EDX and TEM.
| Item Type: | Article |
|---|---|
| Funders: | GSP-MOHE, University of Malaya, Malaysia [Grant No: MO008-2015] |
| Uncontrolled Keywords: | Microemulsion; CeO2 supported catalyst; Oxygen vacancies; Dry reforming; Carbon deposition |
| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
| Divisions: | Faculty of Engineering > Department of Chemical Engineering |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 18 Sep 2023 01:23 |
| Last Modified: | 27 Nov 2024 02:44 |
| URI: | http://eprints.um.edu.my/id/eprint/43052 |
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