Dislocations and crystallite size distribution of cadmium oxide thin films synthesized by spray pyrolysis technique

Mohamed, Liani and Noureddine, Moulay and Mokhtar, Berrahal and Al-Douri, Y. and Djillali, Bensaid and Lakhdar, Boumia and Abd El-Rehim, A. F. and Jadan, M. (2022) Dislocations and crystallite size distribution of cadmium oxide thin films synthesized by spray pyrolysis technique. Materials Science and Engineering B-Advanced Functional Solid-State Materials, 286. ISSN 0921-5107, DOI https://doi.org/10.1016/j.mseb.2022.116055.

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Abstract

Cadmium oxide (CdO) thin films have been successfully deposited on amorphous glass substrates by spray pyrolysis technique at a temperature, 573 degrees K using aqueous solution of cadmium nitrate 4-Hydrate powder with a concentration of 0.1 M. The X-ray diffraction (XRD) studies have revealed that the films exhibit cubic crystal structure. The modified Williamson-Hall and Warren-Averbach methods are used successfully for analyzing the XRD line profile for determining the crystallite size, dislocation densities and crystallite size distribution in CdO thin films. The crystallite size (D) and integral breadths (d) (D = 44.139 nm and d = 32.237 nm) are obtained by the modified Williamson Hall, while the area-weighted average grain sizes and volume-weighted obtained of modified Warren-Averbach method are < x >(vol) = 46, 06nm and < x >(area) = 29,7nm, respectively. The size parameter (L-o), dislocation density (rho), effective outer cut-off radii (R-e) and dislocation arrangement parameter (mu) gotten of Warren-Averbach are 35.53 nm, 2.0 x 10(15) m(-2), 7 nm and 0.31 nm, respectively. The particle size distribution (x) derived of XRD and estimated of size parameter is the size distribution function f(x) of log-normal.

Item Type: Article
Funders: King Khalid University [Grant No: R.G.P. 2/60/43]
Uncontrolled Keywords: CdO; Spray pyrolysis technique; XRD; Crystallite size; Dislocation
Subjects: Q Science > Q Science (General)
Q Science > QC Physics
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 04 Nov 2025 08:24
Last Modified: 04 Nov 2025 08:24
URI: http://eprints.um.edu.my/id/eprint/40783

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