Dicarbocyanine-based organic humidity sensors

Natashah, Fadlan Arif and Sabri, Amirul Ashraf Md and Alzahrani, Hanan and Mamat, Mohamad Hafiz and Roslan, Nur Adilah and Bawazeer, Tahani M. and Alsenany, Nourah and Alsoufi, Mohammad S. and Supangat, Azzuliani (2023) Dicarbocyanine-based organic humidity sensors. Synthetic Metals, 293. ISSN 0379-6779, DOI https://doi.org/10.1016/j.synthmet.2023.117299.

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Abstract

The utilization of organic dicarbocyanine dye-conjugated molecules, specifically 1,1 `-diethyl-4,4 `-dicarbocyanine iodide (DDCI-4), as the sensing film in capacitive-type humidity sensors has been demonstrated. The structural, morphological, and wettability characteristics of the sensing films as well as the performance of the electrode gaps of the devices were analyzed. Aluminum (Al)/DDCI-4/Al capacitive humidity sensors were fabricated using solution-processed spin coating techniques in a planar geometry. In this study, a surface profiler was used to measure the size of electrode gaps, which were 94.87 +/- 1.20 mu m, 391.00 +/- 1.53 mu m, 902.00 +/- 2.08 mu m, and 1906.67 +/- 3.33 mu m. Compared to those with larger gaps (391 mu m, 902 mu m, and 1907 mu m), the device with the smallest gap measured 45 +/- 9.1 fF/%RH with the highest sensitivity. In addition, the hysteresis with response and recovery performances has been studied, revealing the lowest values of 0.31%, 6 s, and 9 s, respectively. It is anticipated that the 1,1 `-diethyl-4,4 `-dicarbocyanine iodide's electronic, ionic, and dipole polarizations are responsible for the excellent performance of dye-based organic humidity sensors.

Item Type: Article
Funders: Universiti Malaya under the Faculty Research Grant GPF080A- 2020
Uncontrolled Keywords: Dye; Conjugated molecules; Humidity sensor; Capacitive; Polarization
Subjects: Q Science > QC Physics
Divisions: Faculty of Science > Department of Physics
Depositing User: Ms Zaharah Ramly
Date Deposited: 24 Nov 2023 08:13
Last Modified: 24 Nov 2023 08:13
URI: http://eprints.um.edu.my/id/eprint/38648

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