Shahid, M. M. and Zhan, Yiqiang and Alizadeh, Mahdi and Sagadevan, Suresh and Paiman, Suriati and Oh, Won Chun (2020) A glassy carbon electrode modified with tailored nanostructures of cobalt oxide for oxygen reduction reaction. International Journal of Hydrogen Energy, 45 (38). pp. 18850-18858. ISSN 03603199, DOI https://doi.org/10.1016/j.ijhydene.2020.05.122.
Full text not available from this repository.Abstract
Herein we report on various surface morphological characteristics of the synthesized cobalt oxide (Co3O4) nanostructures obtained by means of facile one-step hydrothermal method for oxygen reduction reaction (ORR). The synthesized nanostructures of Co3O4 were adequately characterized by field emission scanning electron microscopy (FESEM) fitted with Energy-dispersive X-ray spectroscopy (EDX) elemental mapping, X-ray diffraction (XRD) and Raman techniques. The electrochemical studies were carried out to analyse the performance of as-synthesized catalysts for ORR by cyclic voltammetry (CV), and chronoamperometric (CA) techniques. A higher electrocatalytic response was observed for Co3O4 nanocubes compared with all the other controlled electrodes by CV with a current density of 0.69 mA/cm(2) at a potential value of -0.46 V. The as-synthesized material showed adequate tolerance against methanol observed by CV in the presence of 0.5 M methanol, and good stability when compared with commercial Pt/C catalyst using the CA technique. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Item Type: | Article |
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Funders: | None |
Uncontrolled Keywords: | Cobalt oxide; Hydrothermal; Electrochemical; Oxygen reduction reaction; Fuel cell |
Subjects: | Q Science > Q Science (General) Q Science > QC Physics |
Divisions: | Nanotechnology & Catalysis Research Centre |
Depositing User: | Ms Zaharah Ramly |
Date Deposited: | 28 Oct 2024 13:41 |
Last Modified: | 28 Oct 2024 13:41 |
URI: | http://eprints.um.edu.my/id/eprint/36532 |
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