Ng, Seik Weng and Hu, Shengzhi (2000) Structures that should be Described in Higher-Symmetry, Centrosymmetric Space Groups. Part 2. Jiegou Huaxue, 19 (6). pp. 411-414. ISSN 0254-5861,
Full text not available from this repository.Abstract
The space groups of the transition metal-Schiff base complexes, [ Ni (C5H4NO-2-CH = N-CH2CH2-N = CH-2-C5H4NO) · 2H2O] (ClO4)2 (described in Cc), [Ni(C5H4NO-Z-CH = N-CH(CH3)CH2-N = CH-2-C5H4NO) · 2H2O](ClO4)2 (described in An) and {Cu[(C5H4NO-2-CH = N-N = C(NH2)S] (H2O)}2 (NO3)2 · H2O (described in Cc), have been revised to C2/c. The general descriptions of the first two structures are unchanged in the higher-symmetry setting; for the last structure, the copper atom is re-assigned an octahedral coordination geometry instead of the reported square-pyramidal coordination geometry. The space group of {[CuO2CCH2NHCH2CO2] · (C10H8N2)}2 · 12H2O is similarly revised from P1 to P1. Atomic coordinates for the revised structures are reported.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Simulated intensities; Space-group corrections |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 12 Apr 2021 02:21 |
| Last Modified: | 12 Apr 2021 02:21 |
| URI: | http://eprints.um.edu.my/id/eprint/25858 |
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