de Souza, Marcus V.N. and Howie, R. Alan and Tiekink, Edward R.T. and Wardell, James L. and Wardell, Solange M.S.V. (2009) 7-Chloro-4-[(E)-(3-chlorobenzylidene)hydrazinyl]-1λ4-quinolinium 3-chlorobenzoate. Acta Crystallographica Section E: Structure Reports Online, 65 (12). o3204-o3205. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536809049794.
Full text not available from this repository.Abstract
The title salt, C16H12Cl2N3 +·C7H4ClO2 -, features a non-planar cation, the dihedral angle between the quinolinium and benzene residues being 18.98 (10)°. The cation adopts an E conformation about the C - N bond, and the amine group is oriented towards the quinolinium residue. In the crystal, N - H⋯O hydrogen bonds link two cations with two anions, forming a 20-membered {⋯OCO⋯HNC3NH}2 synthon. The dimeric units are connected into a linear supra-molecular chain along [100] via π-π inter-actions [centroid-centroid distance = 3.5625 (13) Å].
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Hydrazones; Antitubercular Agents; Ethambutol |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 19 Oct 2020 04:07 |
| Last Modified: | 19 Oct 2020 04:07 |
| URI: | http://eprints.um.edu.my/id/eprint/25576 |
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