Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide

Tan, Chee Yu and Saidi, Norshahirah Mohamad and Farhana, N.K. and Omar, Fatin Saiha and Algaradah, Mohammed M. and Bashir, Shahid and Ramesh, Subramaniam and Ramesh, Kasi (2020) Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide. Ionics, 26 (6). pp. 3173-3183. ISSN 0947-7047, DOI https://doi.org/10.1007/s11581-020-03447-2.

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Official URL: https://doi.org/10.1007/s11581-020-03447-2

Abstract

1-Methyl-3-propylimidazolium iodide (MPII) ionic liquid incorporated gel polymer electrolyte (GPE) has successfully enhanced the efficiency of a dye-sensitized solar cell (DSSC). A series of gel polymer electrolytes containing different amounts of MPII were prepared and characterized. A maximum ionic conductivity of 3.99 mS cm−1 was obtained in a GPE containing 10 wt% MPII, which was accompanied by the lowest activation energy. The results from dielectric studies showed typical behaviour for both ɛ’ and ɛ” in which their values decreased with increasing frequency but increased proportionately with temperature. From the results of FESEM, the morphologies of the GPE became slightly rougher after the addition of MPII. Dye-sensitized solar cells were fabricated and characterized using electrochemical impedance spectroscopy (EIS) and photovoltaic studies. DSSC with the best performance (4.35% of efficiency, 9.97 mA cm−2 of JSC, 0.67 V of VOC, and 65.39% of fill factor) was assembled using the GPE with 10 wt% of MPII. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.

Item Type: Article
Funders: University of Malaya Research Grant (RG382-17AFR), Fundamental Research Grant Scheme (FRGS) from the Ministry of Education, Malaysia (FP062-2018A)
Uncontrolled Keywords: Dielectric studies; Dye-sensitized solar cell; Fourier-transform infrared spectroscopy; Gel polymer electrolyte; Ionic liquid
Subjects: Q Science > Q Science (General)
Q Science > QC Physics
Divisions: Faculty of Science > Department of Physics
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 16 Jun 2020 01:32
Last Modified: 16 Jun 2020 01:32
URI: http://eprints.um.edu.my/id/eprint/24836

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