Goh, S.H. and Ong, S.H. (1970) The induced decomposition of t-butyl peroxide in solution. Part II. Kinetic study. Journal of the Chemical Society B: Physical Organic. pp. 870-872. ISSN 0045-6470, DOI https://doi.org/10.1039/J29700000870.
Full text not available from this repository.Abstract
The rate of decomposition of t-butyl peroxide in ρ-chloro-, m-chloro-, and 3,4-dichloro-benzyl methyl ether was found to be reduced in the presence of α-methylstyrene, confirming the occurrence of SH2 attack on t-butyl peroxide by the ether radical. The decomposition of the peroxide in 3,4-dichlorobenzyl methyl ether was of the first order in peroxide, indicating that dimerisation of the ether radical and t-butoxyl radical constituted the main termination step in the chain decomposition of t-butyl peroxide. Data on the relative rate of decomposition of t-butyl peroxide in a variety of solvents indicate that induced decomposition occurs in aromatic and halogenated compounds in addition to ether.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Induced decomposition; t-butyl peroxide; kinetic study |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr Jasny Razali |
| Date Deposited: | 09 Mar 2021 04:21 |
| Last Modified: | 09 Mar 2021 04:21 |
| URI: | http://eprints.um.edu.my/id/eprint/24617 |
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