Low, T.P. and Lee, K.H. (1970) Polar influences in radical reactions. Part VII. Hydrogen abstraction from nuclear-substituted diphenylmethanes, deoxybenzoins, and allylbenzenes by atomic bromine. Journal of the Chemical Society B: Physical Organic. pp. 535-538. ISSN 0045-6470, DOI https://doi.org/10.1039/J29700000535.
Full text not available from this repository.Abstract
The relative reactivities of nuclear-substituted diphenylmethanes, deoxybenzoins (X·C6H4·CH2Bz), and allylbenzenes towards atomic bromine at 80° have been determined by means of competitive reactions by use of allylbenzene, diphenylmethyl methyl ether, and p-bromoethylbenzene, respectively, as reference standard. The results show p-values of -0.93, -0.92, and -0.68 by the Hammett equation for the three systems, the first two systems being better correlated by σ-constants while in the third system σ+-constants gave better correlation in agreement with a previous report. The probable reasons for the correlation with σ-constants are discussed. The ρ-values for these systems fit in well with the consistent inverse relationship with the reactivity values previously observed.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Polar influences; radical reactions; Hydrogen abstraction; nuclear-substituted diphenylmethanes; deoxybenzoins; allylbenzenes by atomic bromine |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr Jasny Razali |
| Date Deposited: | 09 Mar 2021 04:28 |
| Last Modified: | 09 Mar 2021 04:28 |
| URI: | http://eprints.um.edu.my/id/eprint/24615 |
Actions (login required)
 |
View Item |
