Synthesis, characterization and antibacterial activity of novel poly(silyl ether)s based on palm and soy oils

Mohammed, Issam Ahmed and Shahabuddin, Syed and Khanam, Rashmin and Saidur, Rahman (2018) Synthesis, characterization and antibacterial activity of novel poly(silyl ether)s based on palm and soy oils. Polimeros, 28 (5). pp. 406-412. ISSN 0104-1428, DOI https://doi.org/10.1590/0104-1428.10317.

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Official URL: https://doi.org/10.1590/0104-1428.10317

Abstract

In this research, palm oil and soy oil were used as a natural polyol to prepare novel poly(silyl ether)s. Palm oil and soy oil were first converted to monoglyceride by one step via alcoholysis process in the presence of 0.1% CaO as a catalyst. The monoglycerides were characterized by Fourier transform infrared spectrometer (FT-IR), nuclear magnetic resonance (NMR) and iodine test. The novel poly(silyl ether)s were prepared via polycondensation reaction between dimethyldichlorosilane with monoglycerides based on palm and soy oils, respectively. FT-IR, NMR and silicone-29 ( 29 Si NMR) were used to confirm and determine the presence of silicone in the synthesized polymers. Thermal behavior was studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Antibacterial activity of the polymers was screened against three different strains of bacteria, namely Escherichia coli E266, Staphylococcus aureus S276 and Salmonella choleeraesuis 10708.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Antibacterial; Dimethydichlorosilane; Palm oil; Poly(silyl ethers); Polyol; Soy oil
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 15 May 2019 08:42
Last Modified: 15 May 2019 08:42
URI: http://eprints.um.edu.my/id/eprint/21245

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