Suwardi, S.A.N. and Lee, S.M. and Lo, K.M. and Jotani, M.M. and Tiekink, E.R.T. (2017) Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3S,S′:S;κ3S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Structure Reports Online, 73 (3). pp. 429-433. ISSN 2056-9890, DOI https://doi.org/10.1107/S2056989017002705.
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Abstract
The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C - H...S and C - H...π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.
| Item Type: | Article |
|---|---|
| Funders: | Ministry of Higher Education of Malaysia (MOHE) (award No. FP033-2014B) |
| Uncontrolled Keywords: | Crystal structure; Cadmium; Dithio-carbamate; Hirshfeld surface analysis |
| Subjects: | Q Science > Q Science (General) Q Science > QC Physics |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 17 Aug 2018 01:58 |
| Last Modified: | 17 Aug 2018 01:58 |
| URI: | http://eprints.um.edu.my/id/eprint/19016 |
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