Wei, L.Q. and Zeng, M.H. and Ng, S.W. (2010) mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}. Acta Crystallographica Section E: Structure Reports Online, 66 (1). M56-U629. ISSN 1600-5368,
Full text not available from this repository.Abstract
The dinuclear title compound, [Pb-2(C6H8O4)(NO3)(2)(C19H13N5)(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb-II ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Psi-octahedral coordination environment. When weaker Pb center dot center dot center dot O interactions are also considered, the geometry is a Psi-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent molecules are linked into a layer structure by N-H center dot center dot center dot O hydrogen bonds.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | MR Faizal II H |
| Date Deposited: | 23 Dec 2015 03:07 |
| Last Modified: | 30 Jan 2019 08:25 |
| URI: | http://eprints.um.edu.my/id/eprint/15278 |
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