Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate

Caracelli, I. and Moran, P.J.S. and Hinoue, L. and Zukerman-Schpector, J. and Tiekink, E.R.T. (2010) Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate. Acta Crystallographica Section E: Structure Reports Online, 66 (2). O396-U2796. ISSN 1600-5368,

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Abstract

The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 22 Dec 2015 03:20
Last Modified: 31 Jan 2019 01:46
URI: http://eprints.um.edu.my/id/eprint/15212

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