Baul, T.S.B. and Paul, A. and Tiekink, E.R.T. (2010) 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O540-U4334. ISSN 1600-5368,
Full text not available from this repository.Abstract
The title benzene hemisolvate, C17H18N2O3 center dot 0.5C(6)H(6), features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 angstrom) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of inversion. The dihedral angle formed between the benzene rings of the diazo molecule is 7.69 (12)degrees. In the crystal, centrosymmetrically related dimers associate via the eight-membered carboxylic acid dimer synthon, {center dot center dot center dot HOC(=O)}(2), and these are connected into a supramolecular chain along the b axis via C-H center dot center dot center dot O contacts.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 02 Dec 2015 03:34 |
| Last Modified: | 31 Jan 2019 01:43 |
| URI: | http://eprints.um.edu.my/id/eprint/15018 |
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