Wardell, S.M.S.V. and Harrison, W.T.A. and Tiekink, E.R.T. and de Lima, G.M. and Wardell, J.L. (2010) fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1). Acta Crystallographica Section E: Structure Reports Online, 66 (3). M312-U3665. ISSN 1600-5368,
Full text not available from this repository.Abstract
The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 02 Dec 2015 03:31 |
| Last Modified: | 30 Jan 2019 08:24 |
| URI: | http://eprints.um.edu.my/id/eprint/15014 |
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