Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M402-U624. ISSN 1600-5368,
Full text not available from this repository.Abstract
The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P (1) over bar) polymorph [Hall et al. (1993). Aust. J. Chem. 46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.036 (2) angstrom]. In the crystal structure, molecules are arranged into supra-molecular chains along the b axis mediated by C-H center dot center dot center dot pi interactions.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 24 Nov 2015 01:15 |
| Last Modified: | 30 Jan 2019 09:01 |
| URI: | http://eprints.um.edu.my/id/eprint/14778 |
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