Ozonation of a mixture of dialkylphthalates in aqueous solution

Tay, K.S. and Rahman, N.A. and Bin Abas, M.R. (2010) Ozonation of a mixture of dialkylphthalates in aqueous solution. Journal of Chemical Technology and Biotechnology, 85 (5). pp. 726-729.

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Abstract

Ozonation of dimethyl phthalate, diethyl phthalate and dipropyl phthalate was carried out to evaluate the potential of ozonation for phthalate removal from water. Phthalates with longer alkyl chains, which are often more resistant to biodegradation were found to be more degradable than those with shorter alkyl chains. The degradation of phthalates by ozonation follows the pseudo-first-order kinetic model. The rate of phthalates degradation increased exponentially with increasing temperature in the range studied (20 to 50 degrees C) and in proportion with applied ozone dosages. The rate of phthalates degradation was found to increase with increasing pH of the solution from 2.6 to 11.0, and decreased exponentially with increasing initial concentrations of the phthalates. Degradation of phthalates via zonation was found to develop dominantly through direct reaction with hydroxyl radicals. (C) 2010 Society of Chemical Industry

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 11 Nov 2015 02:14
Last Modified: 11 Nov 2015 02:14
URI: http://eprints.um.edu.my/id/eprint/14721

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