Model studies on construction of the oxabicyclic [3.3.1] core of the mulberry Diels–Alder adducts morusalbanol A and 441772-64-1

Tee, Jia Ti and Chee, Chin Fei and Buckle, Michael James Christopher and Lee, Vannajan Sanghiran and Chong, Wei Lim and Khaledi, Hamid and Abd Rahman, Noorsaadah (2015) Model studies on construction of the oxabicyclic [3.3.1] core of the mulberry Diels–Alder adducts morusalbanol A and 441772-64-1. Tetrahedron Letters, 56 (36). pp. 5082-5085. ISSN 0040-4039, DOI https://doi.org/10.1016/j.tetlet.2015.07.042.

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Abstract

Preparation of the oxabicyclic [3.3.1] cores of morusalbanol A and 441772-64-1 was achieved via the intramolecular cyclization of cis–trans (endo) mulberry Diels–Alder adducts. The latter were derived from a hydrogen bond-assisted regioselective Diels–Alder reaction between a chalcone dienophile and a dehydroprenyl diene. Results from these studies provide important insights into the syntheses of morusalbanol A and related mulberry Diels–Alder adducts.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Morusalbanol A; Diels–Alder; Morus alba; Mulberry; Oxabicyclic
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 06 Nov 2015 04:29
Last Modified: 23 Dec 2019 03:59
URI: http://eprints.um.edu.my/id/eprint/14607

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