Abu Affan, M. and Salam, M.A. and Farina, Y. and Ng, S.W. (2010) n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (5). M571-U950. ISSN 1600-5368,
Full text not available from this repository.Abstract
The monodeprotonated Schiff base ligand in the title compound, [Sn(C4H9)(C19H21N4S)Cl-2]center dot CHCl3, N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloroform molecule are disordered over two positions in an 0.67: 0.33 ratio.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 23 Oct 2015 02:22 |
| Last Modified: | 31 Jan 2019 01:38 |
| URI: | http://eprints.um.edu.my/id/eprint/14272 |
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