N-{4-[(3,4-Dimethylphenyl)sulfamoyl]phenyl}acetamide

Khan, I.U. and John, P. and Khizar, S. and Sharif, S. and Tiekink, E.R.T. (2010) N-{4-[(3,4-Dimethylphenyl)sulfamoyl]phenyl}acetamide. Acta Crystallographica Section E: Structure Reports Online, 66 (8). O2134-U2229. ISSN 1600-5368,

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Abstract

Two independent molecules comprise the asymmetric unit of the title compound, C(16)H(18)N(2)O(3)S. Small but significant twists about the (S)N-C and S-C bonds differentiate the molecules but the most obvious difference is found in the relative orientation of the meta-methyl groups, which lie on opposite sides of the molecules. Overall, both molecules adopt a U shape but with significant twisting evident, particularly in the second independent molecule [dihedral angles between benzene rings = 63.90 (13) and 35.78 (11)degrees]. In the crystal, N-H...O hydrogen bonds lead to supramolecular chains with a tubular topology propagating in [100] and C-H...O contacts cross-link the chains.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 05 Feb 2015 02:05
Last Modified: 31 Jan 2019 04:36
URI: http://eprints.um.edu.my/id/eprint/12582

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