Gunasekaran, N. and Karvembu, R. and Ng, S.W. and Tiekink, E.R.T. (2010) 1-Benzoyl-3,3-bis(propan-2-yl)thiourea. Acta Crystallographica Section E: Structure Reports Online, 66 (8). O2113-U2019. ISSN 1600-5368,
Full text not available from this repository.Abstract
Two independent thiourea derivatives comprise the asymmetric unit of the title compound, C(14)H(20)N(2)OS. The major difference between the molecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5 (2) and -19.9 (2)degrees for the two independent molecules]. The thiocarbonyl and carbonyl groups lie to opposite sides of the molecule as there are twists about the central N-S bond [torsion angles = 83.90 (15) and 81.77 (15)degrees]. Supramolecular chains extending parallel to [101] with a stepped topology and mediated by N-H...O hydrogen bonding feature in the crystal structure. C-H...O and C-H...pi interactions are also present.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 05 Feb 2015 02:05 |
| Last Modified: | 31 Jan 2019 04:11 |
| URI: | http://eprints.um.edu.my/id/eprint/12577 |
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