Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate

Thy, C.K. and Lo, K.M. and Ng, S.W. (2010) Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M992-U1217. ISSN 1600-5368,

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Abstract

The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]center dot 0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) A in one ring and by 0.690 (1) A for the other. The two planes are aligned at an angle of 59.6 (1)degrees. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:12
Last Modified: 30 Jan 2019 08:41
URI: http://eprints.um.edu.my/id/eprint/12543

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