Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex

Shahid, M. and Hamid, M. and Mazhar, M. and Malik, M.A. and Raftery, J. (2010) Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M949-U843. ISSN 1600-5368,

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Abstract

The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 A away, are orthogonal to this plane at the metal site.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:11
Last Modified: 30 Jan 2019 09:10
URI: http://eprints.um.edu.my/id/eprint/12538

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