Mohammadnezhad, G. and Ghanbarpour, A.R. and Amini, M.M. and Ng, S.W. (2010) Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M963-U938. ISSN 1600-5368,
Full text not available from this repository.Abstract
The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetry-related PbII atoms, forming the dinuclear compound. Aside from the six atoms connected to the PbII atom by regular coordination bonds, the structure features a long Pb...O interaction [3.145 (3) A] that gives rise to a distorted Psi-square-antiprismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 04 Feb 2015 02:14 |
| Last Modified: | 31 Jan 2019 04:45 |
| URI: | http://eprints.um.edu.my/id/eprint/12535 |
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