Keng, C.T. and Lo, K.M. and Ng, S.W. (2010) Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M1008-U1378. ISSN 1600-5368,
Full text not available from this repository.Abstract
Two nicotinate binding modes are observed in the dinuclear title compound, [Sn-2(C7H6Br)(4)(C6H4NO2)(4)(H2O)(2)]: in the first, a terminal O,O'-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C2SnNO4 pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O-H...N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O-H...O interactions are also observed.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 04 Feb 2015 02:14 |
| Last Modified: | 31 Jan 2019 04:30 |
| URI: | http://eprints.um.edu.my/id/eprint/12533 |
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