catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]

Keng, C.T. and Lo, K.M. and Ng, S.W. (2010) catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M978-U1100. ISSN 1600-5368,

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Abstract

Adjacent units of the title polymeric complex, [Sn(C7H6F)(3)(C8H12NO2S2)], are bridged by the carboxylate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C3SnO2 trigonal-bipyramidal coordination and is displaced by 0.113 (2) A out of the C3Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:16
Last Modified: 31 Jan 2019 04:30
URI: http://eprints.um.edu.my/id/eprint/12532

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