Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)

Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1064-U301. ISSN 1600-5368,

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Abstract

Tris(2-chlorobenzyl) tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked to the other molecule by an N-H center dot center dot center dot N hydrogen bond. In the second molecule, two of the chlorobenzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both molecules shows a distorted tetrahedral SnSC(3) coordination.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:57
Last Modified: 31 Jan 2019 04:31
URI: http://eprints.um.edu.my/id/eprint/12412

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