Fairuz, Z.A. and Aiyub, Z. and Abdullah, Z. and Ng, S.W. and Tiekink, E.R.T. (2010) Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1049-U173. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 27 Jan 2015 07:57 |
| Last Modified: | 31 Jan 2019 04:04 |
| URI: | http://eprints.um.edu.my/id/eprint/12410 |
Actions (login required)
 |
View Item |
