Gunasekaran, N. and Karvembu, R. and Ng, S.W. and Tiekink, E.R.T. (2010) 3-Benzoyl-1,1-dibenzylthiourea. Acta Crystallographica Section E: Structure Reports Online, 66 (10). O2572-U574. ISSN 1600-5368,
Full text not available from this repository.Abstract
Two independent thiourea molecules comprise the asymmetric unit of the title compound, C(22)H(20)N(2)OS. The central N-C(=S)N(H)C(=O) atoms in each molecule are virtually superimposable and each is twisted [C-N-C-S torsion angles = 121.3 (3) and -62.3 (4)degrees]. The molecules differ only in terms of the relative orientations of the benzyl benzene rings [major difference between the C-N-C-C torsion angles of -146.6 (3) and -132.9 (3)degrees]. The presence of N-H center dot center dot center dot S hydrogen bonding leads to the formation of supramolecular chains along the a axis. These are consolidated in the crystal packing by C-H center dot center dot center dot O interactions. The crystal was found to be a combined non-merohedral and racemic twin (twin law (1) over bar 00/0 (1) over bar0/001), with the fractional contribution of the minor components being approximately 9 and 28%.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 19 Jan 2015 03:41 |
| Last Modified: | 31 Jan 2019 04:12 |
| URI: | http://eprints.um.edu.my/id/eprint/12216 |
Actions (login required)
 |
View Item |
