Catena-Poly[bis(mu(4)-adipato-1:2:1 `:2 `kappa O-4(1):O-1 `:O-4:O-4 `)bis(N,N-dimethylformamide)-1 kappa O,2 kappa O-dicopper(II)]

Wu, Guo-Yun and Ng, S.W. (2010) Catena-Poly[bis(mu(4)-adipato-1:2:1 `:2 `kappa O-4(1):O-1 `:O-4:O-4 `)bis(N,N-dimethylformamide)-1 kappa O,2 kappa O-dicopper(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1258-U841. ISSN 1600-5368,

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Abstract

In the title polymeric complex, [Cu-2(C6H8O4)(2)(C3H7NO)(2)](n), the carboxylate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion- related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper (II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF molecule whereas the four basal sites are occupied by carboxylate O atoms.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 30 Jan 2019 08:28
URI: http://eprints.um.edu.my/id/eprint/12205

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