Ou, Guang-Chuan and Ng, S.W. (2010) (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1468-U1223. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 14 Jan 2015 01:59 |
| Last Modified: | 31 Jan 2019 05:10 |
| URI: | http://eprints.um.edu.my/id/eprint/11997 |
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