catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]

Han, Yin-Feng and Ng, S.W. (2010) catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1431-U884. ISSN 1600-5368,

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Abstract

In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H center dot center dot center dot O hydrogen bonds involving the coordinated and uncoordinated water molecules.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:00
Last Modified: 31 Jan 2019 04:20
URI: http://eprints.um.edu.my/id/eprint/11992

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