Synthesis and structural consideration of metal-organic framework (MOF) coordination polymer with various metal linker ratios

Misran, H. and Aminuddin, A.M. and Zini, F.A.M. and Singh, R. (2011) Synthesis and structural consideration of metal-organic framework (MOF) coordination polymer with various metal linker ratios. Key Engineering Materials, 462-46 . Engineering, pp. 1103-1108.

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Abstract

Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn(4)O(BDC)(3) were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7.

Item Type: Book
Additional Information: Times Cited: 0 Misran, Halina Aminuddin, Atiah Mohd Zini, Faizul Akmal Mohd Singh, Ramesh 8th International Conference on Fracture and Strength of Solids (FEOFS) 2010 Jun 07-09, 2010 Kuala Lumpur, MALAYSIA Malaysian Assoc Comp Mech, Far E & Ocean Fracture Soc, Malaysian Tribol Soc, Malaysian Structural Res Grp----- you can e-mail to me for the full text of my jurnal at ramesh79@um.edu.my
Subjects: T Technology > TS Manufactures
Divisions: Faculty of Engineering
Depositing User: Mr. Mohammed Salim Abd Rahman
Date Deposited: 03 Jul 2013 02:31
Last Modified: 03 Jul 2013 02:31
URI: http://eprints.um.edu.my/id/eprint/6541

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