Aqua{2-(morpholin-4-yl)-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)manganese(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Aqua{2-(morpholin-4-yl)-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)manganese(II). Acta Crystallographica Section E: Structure Reports Online, 67. M928-U1007. ISSN 1600-5368

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Abstract

In the title compound, [Mn(NCS)(2)(C13H19N3O)(H2O)], the Schiff base acts as an N,N',N ''-tridentate ligand, forming two five-membered chelating rings with the Mn-II atom. The distorted octahedral geometry around the metal atom is completed by two cis-positioned N-bound thiocyanate ligands and one water molecule. In the crystal, adjacent molecules are linked through O-H center dot center dot center dot O, O-H center dot center dot center dot S and C-H center dot center dot center dot S hydrogen bonds into a three-dimensional supra-molecular structure. An intramolecular C-H center dot center dot center dot O hydrogen bond also occurs.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 26 Mar 2013 01:19
Last Modified: 30 Jan 2019 01:02
URI: http://eprints.um.edu.my/id/eprint/5251

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