Single-atom catalysts for thermochemical gas-phase reactions

Ibrahim, Abdulrauf Onimisi and Halilu, Ahmed and Daud, Wan Mohd Ashri Wan and Abdul Patah, Muhamad Fazly and Juan, Joon Ching (2022) Single-atom catalysts for thermochemical gas-phase reactions. Molecular Catalysis, 529. ISSN 2468-8231, DOI https://doi.org/10.1016/j.mcat.2022.112535.

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Abstract

Catalytic gas-phase reactions have gained industrial applicability in the production of chemicals, fuels, and environmental remediation. However, conventional heterogeneous catalysts for gas-phase reactions contain precious metals, which have low utilization efficiency of metal atoms and are expensive, and therefore need to be improved to achieve industrial scalability. Therefore, single-atom catalysis has emerged as a new paradigm for dispersing isolated noble metals on a suitable support material. Herein, this review analyzed recent advances in single-atom catalysts (SACs) for oxidation of carbon monoxide, abatement of formaldehyde, reduction of ni-trogen oxides, and hydrogenation of carbon dioxide. Various synthesis methods of different SACs were elucidated and highlighted for the thermochemical gas-phase reactions. Furthermore, the mechanism, challenges, and prospects of the SACs for gas-phase reactions were described. This review is significant to serve as a reference for current and prospective thermochemical gas-phase reactions driven by SACs.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Catalysis; Gas -phase reaction; Single -atom catalysts; Carbon monoxide; Acetylene
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Engineering
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 13 Sep 2023 06:48
Last Modified: 13 Sep 2023 06:48
URI: http://eprints.um.edu.my/id/eprint/41202

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