Amin, N. A. A. M. and Said, S. M. and Salleh, M. F. M. and Muhammad Afifi, Amalina and Ibrahim, N. M. J. N. and Hasnan, M. M. I. M. and Tahir, M. and Hashim, N. Z. I. (2023) Review of Fe-based spin crossover metal complexes in multiscale device architectures. Inorganica Chimica Acta, 544. ISSN 0020-1693, DOI https://doi.org/10.1016/j.ica.2022.121168.
Full text not available from this repository.Abstract
Metal complexes involving d4-d7 first-row transition metals exhibit spin-crossover (SCO) behaviour between low -spin and high-spin states in response to external stimuli such as temperature, pressure, voltage control and light irradiation. They are of interest in functional devices such as sensors, molecular electronics, spintronic devices, and well as memory and information processing applications. In particular, many electronic devices exploiting the SCO phenomena contain Fe-based SCO materials, which have shown significant performance. This paper reviews the state of the art and configurations of such functional devices on a range of scales. Utilisation of SCO functionality ranging from single molecule junctions to nanoparticles and thin films incorporated into horizontal and vertical junction device architectures, will be elaborated. This review provides a systematic overview in the characteristics of Fe-based SCO functional device and their corresponding performance. This understanding provides a pathway for further optimization of Fe-based SCO technologies in a wide range of electronic applications.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Spin crossover; Molecular junctions; Molecular electronics; Electrical switching; Spintronics; Switching devices |
| Subjects: | T Technology > T Technology (General) T Technology > TJ Mechanical engineering and machinery |
| Divisions: | Faculty of Engineering Faculty of Engineering > Department of Mechanical Engineering |
| Depositing User: | Ms Zaharah Ramly |
| Date Deposited: | 01 Nov 2024 01:35 |
| Last Modified: | 01 Nov 2024 01:35 |
| URI: | http://eprints.um.edu.my/id/eprint/38951 |
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