Synthesis and characterization of low-cost carbon nanotubes by chemical vapor deposition for aluminum removal from aqueous solution

Basheer, Alfarooq O. and Hanafiah, Marlia M. and Alsaadi, Mohammed Abdulhakim and Yaacob, Wan Zuhairi Wan and Al-Douri, Y. and Bouhemadou, A. (2021) Synthesis and characterization of low-cost carbon nanotubes by chemical vapor deposition for aluminum removal from aqueous solution. Desalination and Water Treatment, 214. pp. 440-451. ISSN 1944-3994, DOI https://doi.org/10.5004/dwt.2021.26749.

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Abstract

This study investigates novel multi-walled carbon nanotubes (MWCNTs) grown on agricultural waste, using loaded iron nanoparticles as catalyst templates and acetylene as carbon source through chemical vapor deposition under specific conditions, to wit: 550 degrees C reaction temperature, 47 min reaction time, and 1 gas ratio. The specifications of MWCNTs are analyzed and characterized with the use of field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, ther- mogravimetric analysis, Brunauer-Emmett-Teller surface area analysis, and zeta potential analysis. The results reveal that MWCNTs have high quality and unique morphologies. The removal and capacity of Al are optimized through response surface methodology, whilst the adsorption kinetics results are well ascribed to the pseudo-second-order model, the isotherm data are effectively fitted using a Langmuir model. The maximum adsorption capacity is 393.52 mg/g. The results demonstrate that MWCNTs can be regarded as a new low-cost adsorbent in wastewater treatment for the removal of Al-3(+).

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Carbon nanotubes; Chemical vapour deposition; Response surface methodology; Adsorption
Subjects: Q Science > Q Science (General)
T Technology > T Technology (General)
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms Zaharah Ramly
Date Deposited: 15 Aug 2022 02:54
Last Modified: 15 Aug 2022 02:54
URI: http://eprints.um.edu.my/id/eprint/28533

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