Influencing factors in the synthesis of photoactive nanocomposites of zno/sio2-porous heterostructures from montmorillonite and the study for methyl violet photodegradation

Fatimah, Is and Purwiandono, Gani and Citradewi, Putwi Widya and Sagadevan, Suresh and Oh, Won-Chun and Doong, Ruey-an (2021) Influencing factors in the synthesis of photoactive nanocomposites of zno/sio2-porous heterostructures from montmorillonite and the study for methyl violet photodegradation. Nanomaterials, 11 (12). ISSN 2079-4991, DOI https://doi.org/10.3390/nano11123427.

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Abstract

In this work, photoactive nanocomposites of ZnO/SiO2 porous heterostructures (PCHs) were prepared from montmorillonite clay. The effects of preparation methods and Zn content on the physicochemical features and photocatalytic properties were investigated. Briefly, a comparison of the use of hydrothermal and microwave-assisted methods was done. The Zn content was varied between 5 and 15 wt% and the characteristics of the nanomaterials were also examined. The physical and chemical properties of the materials were characterized using X-ray diffraction, diffuse-reflectance UV-Vis, X-ray photoelectron spectroscopy, and gas sorption analyses. The morphology of the synthesized materials was characterized through scanning electron microscopy and transmission electron microscopy. The photocatalytic performance of the prepared materials was quantified through the photocatalytic degradation of methyl violet (MV) under irradiation with UV and visible light. It was found that PCHs exhibit greatly improved physicochemical characteristics as photocatalysts, resulting in boosting photocatalytic activity for the degradation of MV. It was found that varied synthesis methods and Zn content strongly affected the specific surface area, pore distribution, and band gap energy of PCHs. In addition, the band gap energy was found to govern the photoactivity. Additionally, the surface parameters of the PCHs were found to contribute to the degradation mechanism. It was found that the prepared PCHs demonstrated excellent photocatalytic activity and reusability, as seen in the high degradation efficiency attained at high concentrations. No significant changes in activity were seen until five cycles of photodegradation were done.

Item Type: Article
Funders: Kementrian Riset-Badan Riset Nasional, Republic of Indonesia via World Class Research Grant [2817/E4.1/KK.04.05/2021 018/DirDPPM/70/DPPM/WCR-KEMDIKBUDRISTEK/VII/2021]
Uncontrolled Keywords: Advanced oxidation Process; Photocatalyst; Porous clay heterostructure; Photodegradation
Subjects: Q Science > Q Science (General)
T Technology > T Technology (General)
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms Zaharah Ramly
Date Deposited: 02 Aug 2022 01:21
Last Modified: 02 Aug 2022 01:21
URI: http://eprints.um.edu.my/id/eprint/28267

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