Taib, Mohamad Nurul Azman Mohammad and Yehye, Wageeh Abdulhadi and Julkapli, Nurhidayatullaili Muhd (2019) Influence of Crosslinking Density on Antioxidant Nanocellulose in Bio-degradation and Mechanical Properties of Nitrile Rubber Composites. Fibers and Polymers, 20 (1). pp. 165-176. ISSN 1229-9197, DOI https://doi.org/10.1007/s12221-019-8575-y.
Full text not available from this repository.Abstract
Nanocellulose antioxidant (Aox-NCC) was used as reinforcement and crosslinking agent in nitrile butadiene rubber (NBR) composites. The crosslinking density and volume of rubber bonded in the matrix were increased up to 3 phr and no significant improvement between 4 phr and 5 phr was recorded. The interactions of gallic acid and NCC was found to occur between the -OH and -COOH groups, as revealed by Fourier Transform Infra-Red (FTIR) and Nuclear Magnetic Resonance (NMR) analysis. Crystallinity index of Aox-NCC was increased more than 11 %, recorded by X-ray diffraction (XRD) analysis. Meanwhile, the thermal stability of Aox-NCC was increased 30°C, analyzed by thermogravimetry (TG). With the addition of 3 phr Aox-NCC, tensile strength and modulus at 500 % for NBR composites were increased significantly up to 20 %. There was no significant improvement on modulus at 100 %, modulus at 300 %, elongation at break and tear strength. The degradability of NBR composites within 6 months period was improved significantly at 5 phr of Aox- NCC. Increase in carbonyl group after soil burial test with the existence of cracks, voids and degradable parts of NBR composites were revealed. This demonstrated that, Aox-NCC plays a secure function to reinforce NBR composites. © 2019, The Korean Fiber Society, The Korea Science and Technology Center.
| Item Type: | Article |
|---|---|
| Funders: | Postgraduate Research Grant (PPP) (PG238-2015A: Effects on surface acetylated nano-crystalline cellulose (NCC) reinforced in nitrile butadiene rubber (NBR) composite) |
| Uncontrolled Keywords: | Biodegradable; Cellulose; Composites; Morphology; Nanocrystals |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) |
| Divisions: | Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 08 Jan 2020 06:05 |
| Last Modified: | 08 Jan 2020 06:05 |
| URI: | http://eprints.um.edu.my/id/eprint/23344 |
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