Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor

Wong, S.P. and Gan, C.Y. and Lim, K.H. and Ting, K.N. and Low, Y.Y. and Kam, T.S. (2015) Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor. Organic Letters, 17 (14). pp. 3628-3631. ISSN 1523-7060, DOI https://doi.org/10.1021/acs.orglett.5b01757.

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Official URL: http://dx.doi.org/10.1021/acs.orglett.5b01757

Abstract

A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogenetic pathway from a pericine precursor is presented.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Alkaloids; Indole Alkaloids; Malaysia; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Polycyclic Compounds; X-Ray Diffraction
Subjects: Q Science > Q Science (General)
Q Science > QA Mathematics > QA75 Electronic computers. Computer science
Q Science > QD Chemistry
R Medicine
T Technology > TA Engineering (General). Civil engineering (General)
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 28 Sep 2018 02:17
Last Modified: 28 Sep 2018 02:17
URI: http://eprints.um.edu.my/id/eprint/19443

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