Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3S,S′:S;κ3S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

Suwardi, S.A.N. and Lee, S.M. and Lo, K.M. and Jotani, M.M. and Tiekink, E.R.T. (2017) Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3S,S′:S;κ3S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Structure Reports Online, 73 (3). pp. 429-433. ISSN 2056-9890

[img]
Preview
PDF (Open Access)
Bis(μ_2-N-methyl-N-phenyl-dithio-carbamato).pdf

Download (1MB)
Official URL: http://dx.doi.org/10.1107/S2056989017002705

Abstract

The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C - H...S and C - H...π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

Item Type: Article
Uncontrolled Keywords: Crystal structure; Cadmium; Dithio-carbamate; Hirshfeld surface analysis
Subjects: Q Science > Q Science (General)
Q Science > QC Physics
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 17 Aug 2018 01:58
Last Modified: 17 Aug 2018 01:58
URI: http://eprints.um.edu.my/id/eprint/19016

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year