Advancement in heterogeneous base catalyzed technology: An efficient production of biodiesel fuels

Lee, H.V. and Juan, J.C. and Taufiq-Yap, Y.H. and Kong, P.S. and Rahman, N.A. (2015) Advancement in heterogeneous base catalyzed technology: An efficient production of biodiesel fuels. Journal of Renewable and Sustainable Energy, 7 (3). p. 46. ISSN 1941-7012

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Abstract

Price fluctuation of petroleum-based diesel, climate change, emerging mandate obligations, availability of new feedstock and the upgrading of conversion technologies are expected to drive biodiesel market to grow robustly in the next coming 10 years. However, the current bottleneck in biodiesel production is the lack of economical sustainable conversion technologies. Generally, industrial production of biodiesel is greatly relied on alkaline homogeneous transesterification reaction. Limitation of the technology, such as multistep process which incur extra pre-step for high acid oil treatment and post-step for biodiesel purification and alkali washing as diminished the economic feasibility and low environmental impact of the entire biodiesel process. Heterogeneous catalysis offers immense potential to develop simple transesterification process, including one step reaction, easy separation, reusability of catalyst, and green reaction. Thus, the aim of this paper is to review the biodiesel production technologies such as blending, micro-emulsion, pyrolysis, and transesterification. Furthermore, recent studies on heterogeneous catalyzed transesterification were presented by discussing the issues such as catalytic performance on different types of biodiesel feedstock, transesterification reaction conditions, limitations encountered by heterogeneous catalysts, and reusability of solid catalysts. The heterogeneous catalysts presented in this review is mainly focused on solid base catalysts, which include single metal oxides, supported metal oxide, binary metal oxide, hydrotalcite, and natural waste shell-based catalyst. Furthermore, current perspectives on application of heterogeneous catalyzed technology in biodiesel industry were discussed herein. (C) 2015 AIP Publishing LLC.

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Additional Information: ISI Document Delivery No.: CM4WA Times Cited: 0 Cited Reference Count: 195 Cited References: Abdullah AZ, 2009, FUEL PROCESS TECHNOL, V90, P958, DOI 10.1016/j.fuproc.2009.03.023 Alba-Rubio AC, 2010, CATAL TODAY, V149, P281, DOI 10.1016/j.cattod.2009.06.024 Albuquerque MCG, 2008, APPL CATAL A-GEN, V347, P162, DOI 10.1016/j.apcata.2008.06.016 Albuquerque MCG, 2008, APPL CATAL A-GEN, V334, P35, DOI 10.1016/j.apcata.2007.09.028 Albuquerque MCG, 2009, J MOL CATAL A-CHEM, V300, P19, DOI 10.1016/j.molcata.2008.10.033 Alonso DM, 2010, CATAL TODAY, V158, P114, DOI 10.1016/j.cattod.2010.05.003 Alonso DM, 2007, CATAL COMMUN, V8, P2074, DOI 10.1016/j.catcom.2007.04.003 ANDO T, 1987, TETRAHEDRON LETT, V28, P1421, DOI 10.1016/S0040-4039(00)95943-4 Antunes WM, 2008, CATAL TODAY, V133, P548, DOI 10.1016/j.cattod.2007.12.055 Aransiola EF, 2014, BIOMASS BIOENERG, V61, P276, DOI 10.1016/j.biombioe.2013.11.014 Arzamendi G, 2007, CHEM ENG J, V134, P123, DOI 10.1016/j.cej.2007.03.049 Arzamendi G, 2008, CATAL TODAY, V133, P305, DOI 10.1016/j.cattod.2007.11.029 Ashraful AM, 2014, ENERG CONVERS MANAGE, V80, P202, DOI 10.1016/j.enconman.2014.01.037 Baba T, 2000, CATAL SURV JPN, V4, P17, DOI 10.1023/A:1019092222785 Babu NS, 2008, ENERG FUEL, V22, P1965, DOI 10.1021/ef700687w Bankovic-Ilie IB, 2014, RENEW SUST ENERG REV, V32, P238, DOI 10.1016/j.rser.2014.01.038 Barakos N, 2008, BIORESOURCE TECHNOL, V99, P5037, DOI 10.1016/j.biortech.2007.09.008 Benjapornkulaphong S, 2009, CHEM ENG J, V145, P468, DOI 10.1016/j.cej.2008.04.036 Bloch M., 2006, VIGO IMPROVED GLYCER Boey PL, 2011, FUEL, V90, P2353, DOI 10.1016/j.fuel.2011.03.002 Boey PL, 2011, J AM OIL CHEM SOC, V88, P283, DOI 10.1007/s11746-010-1660-4 Boey PL, 2009, BIORESOURCE TECHNOL, V100, P6362, DOI 10.1016/j.biortech.2009.07.036 Boey PL, 2009, J OLEO SCI, V58, P499, DOI 10.5650/jos.58.499 Bota RM, 2010, CATAL TODAY, V152, P99, DOI 10.1016/j.cattod.2010.01.002 Bournay L, 2005, CATAL TODAY, V106, P190, DOI 10.1016/j.cattod.2005.07.181 Boz N, 2009, APPL CATAL B-ENVIRON, V89, P590, DOI 10.1016/j.apcatb.2009.01.026 Breck D. 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V. Juan, J. C. Taufiq-Yap, Y. H. Kong, P. S. Rahman, N. A. Engineering, Faculty /I-7935-2015 Engineering, Faculty /0000-0002-4848-7052 Malaysia Ministry of Education (MOE) under FRGS Grant FP056-2013B, FP054-2013B; University of Malaya (UMRG) RP 025A/025B/025C-14AET; grand challenge Grant GC001B-14AET The authors would like to thank Malaysia Ministry of Education (MOE) for sponsoring this work under FRGS Grant (Nos. FP056-2013B and FP054-2013B), University of Malaya (UMRG Grant No. RP 025A/025B/025C-14AET), and grand challenge Grant (No. GC001B-14AET). 0 AMER INST PHYSICS MELVILLE J RENEW SUSTAIN ENER
Uncontrolled Keywords: Response-surface methodology, metal-oxide catalysts, mg-al, hydrotalcites, palm kernel oil, double hydroxide catalysts, jatropha-curcas oil, soybean oil, calcium-oxide, sunflower oil, vegetable-oils,
Subjects: T Technology > T Technology (General)
T Technology > TP Chemical technology
Divisions: Faculty of Engineering
Depositing User: Mr Jenal S
Date Deposited: 02 Mar 2016 06:19
Last Modified: 02 Mar 2016 06:19
URI: http://eprints.um.edu.my/id/eprint/15651

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