Model studies on construction of the oxabicyclic [3.3.1] core of the mulberry Diels–Alder adducts morusalbanol A and 441772-64-1

Tee, J.T. and Chee, C.F. and Buckle, M.J.C. and Lee, V.S. and Chong, W.L. and Khaledi, H. and Rahman, N.A. (2015) Model studies on construction of the oxabicyclic [3.3.1] core of the mulberry Diels–Alder adducts morusalbanol A and 441772-64-1. Tetrahedron Letters, 56 (36). pp. 5082-5085. ISSN 0040-4039

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Abstract

Preparation of the oxabicyclic [3.3.1] cores of morusalbanol A and 441772-64-1 was achieved via the intramolecular cyclization of cis–trans (endo) mulberry Diels–Alder adducts. The latter were derived from a hydrogen bond-assisted regioselective Diels–Alder reaction between a chalcone dienophile and a dehydroprenyl diene. Results from these studies provide important insights into the syntheses of morusalbanol A and related mulberry Diels–Alder adducts.

Item Type: Article
Uncontrolled Keywords: Morusalbanol A; Diels–Alder; Morus alba; Mulberry; Oxabicyclic
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 06 Nov 2015 04:29
Last Modified: 06 Nov 2015 04:29
URI: http://eprints.um.edu.my/id/eprint/14607

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