Production of greenhouse gas free hydrogen by thermocatalytic decomposition of methane – A review

Ashik, U.P.M. and Daud, Wan Mohd Ashri Wan and Abbas, H.F. (2015) Production of greenhouse gas free hydrogen by thermocatalytic decomposition of methane – A review. Renewable and Sustainable Energy Reviews, 44. pp. 221-256. ISSN 1364-0321, DOI https://doi.org/10.1016/j.rser.2014.12.025.

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Abstract

Thermocatalytic decomposition of methane (TCD) is a fully green single step technology for producing hydrogen and nano-carbon. This review studying all development in laboratory-scale research on TCD, especially the recent advances like co-feeding effect and catalyst regeneration for augmenting the productivity of the whole process. Although a great success on the laboratory-scale has been fulfilled, TCD for greenhouse gas (GHG) free hydrogen production is still in its infancy. The need for commercialization of TCD is greater than ever in the present situation of huge GHG emission. TCD usually examined over various kind of catalysts, such as monometallic, bimetallic, trimetallic, combination of metal-metal oxide, carbonaceous and/or metal doped carbon catalysts. Deactivation of catalysts is the prime drawback found in TCD process. Catalyst regeneration and co-feeding of methane with other hydrocarbon are the two solutions put forwarded in accordance to overcome deactivation hurdle. Higher amount of co-feed hydrocarbon in situ produce more amount of highly active carbonaceous deposits which assist further methane decomposition to produce additional hydrogen to a great extent. The methane conversion rate increases with increase in the temperature and decreases with the flow rate in the co-feeding process in a similar manner as observed in normal TCD. The presence of co-components in the post-reaction stream is a key challenge tackled in the co-feeding and regeneration. Hence, this review hypothesizing the integration of hydrogen separation membrane in to methane decomposition reactor for online hydrogen separation. (C) 2014 Elsevier Ltd. All rights reserved.

Item Type:	Article
Funders:	University of Malaya, Malaysia UM.C/HIR/MOHE/ENG/11
Additional Information:	ISI Document Delivery No.: CD8DB Times Cited: 0 Cited Reference Count: 208 Cited References: Abbas HF, 2010, INT J HYDROGEN ENERG, V35, P141, DOI 10.1016/j.ijhydene.2009.10.072 Abbas HF, 2009, INT J HYDROGEN ENERG, V34, P6231, DOI 10.1016/j.ijhydene.2009.05.143 Abbas HF, 2011, INT J HYDROGEN ENERG, V36, P8985, DOI 10.1016/j.ijhydene.2011.05.005 Abbas HF, 2009, INT J HYDROGEN ENERG, V34, P8034, DOI 10.1016/j.ijhydene.2009.08.014 Abbas HF, 2010, INT J HYDROGEN ENERG, V35, P12268, DOI 10.1016/j.ijhydene.2010.08.036 Abbas HF, 2010, APPL CATAL A-GEN, V388, P232, DOI 10.1016/j.apcata.2010.08.057 Abbas HF, 2010, INT J HYDROGEN ENERG, V35, P1160, DOI 10.1016/j.ijhydene.2009.11.036 Abbott HL, 2008, J CATAL, V254, P27, DOI 10.1016/j.jcat.2007.11.013 Acha E, 2013, INT J HYDROGEN ENERG, V38, P7659, DOI 10.1016/j.ijhydene.2012.11.010 Adamska A, 2010, ENERG FUEL, V24, P3307, DOI 10.1021/ef9014179 Adhikari S, 2006, IND ENG CHEM RES, V45, P875, DOI 10.1021/ie050644l Aiello R, 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P. M. Daud, W. M. A. Wan Abbas, Hazzim F. University of Malaya, Malaysia UM.C/HIR/MOHE/ENG/11 The authors gratefully acknowledge financial support from the Postgraduate Research Fund (UM.C/HIR/MOHE/ENG/11), University of Malaya, Malaysia. 0 PERGAMON-ELSEVIER SCIENCE LTD OXFORD RENEW SUST ENERG REV
Uncontrolled Keywords:	Catalytic methane decomposition, Hydrogen production, Metal-carbon, catalysts, Methane co-feeding, Hydrogen separation membrane, THERMO-CATALYTIC DECOMPOSITION, FLUIDIZED-BED REACTOR, SUPPORTED, NICKEL-CATALYSTS, ACTIVATED CARBON CATALYST, COAL-LIQUEFACTION RESIDUE, ZEOLITE-BASED CATALYSTS, RANEY-TYPE CATALYSTS, NI-BASED CATALYSTS, COX-FREE HYDROGEN, CH4 DECOMPOSITION,
Subjects:	T Technology > T Technology (General) T Technology > TP Chemical technology
Divisions:	Faculty of Engineering
Depositing User:	Mr Jenal S
Date Deposited:	22 Sep 2015 00:28
Last Modified:	08 Nov 2019 09:09
URI:	http://eprints.um.edu.my/id/eprint/14029

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