Ng, S.W. (2008) Poly[(μ(3)-nicotinato-κO:O':N)(μ(2)-nicotinato-κO,O':N)iron(II)]. Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 5). m728. ISSN 1600-5368, DOI 21202251.

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Official URL: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC296119...


In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octa-hedral coordination geometry but one of the Fe-O bonds is somewhat long [2.522 (2) Å].

Item Type: Article
Uncontrolled Keywords: Chemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 21 Apr 2011 03:16
Last Modified: 31 Jan 2019 02:18
URI: http://eprints.um.edu.my/id/eprint/858

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