N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide

Ariffin, Azhar and Ng, S.W. and Yehye, W.A. and Rahman, N.A. (2010) N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide. Acta Crystallographica Section E: Structure Reports Online, 66 (4). O734-U1479. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810006884.

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In the title compound, C(30)H(36)N(2)O(2)S, the dihedral angle between the two aromatic rings of the biphenyl residue is 31.2 (1)degrees. The two methylene C atoms subtend an angle of 99.9 (1)degrees at the S atom. In the crystal, molecules form inversion dimers linked by pairs of N-H center dot center dot center dot O hydrogen bonds. The hydroxyl group is shielded by the tert-butyl residues and is therefore not involved in any hydrogen bonding.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Dihedral angle; Aromatic rings; Biphenyl residue; Crystal; Inversion dimers; Hydrogen bonds; Hydroxyl group; Tert-butyl residues hydrogen bonding
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 03 Jul 2013 04:19
Last Modified: 31 Jan 2019 01:03
URI: http://eprints.um.edu.my/id/eprint/8091

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