3-Acetyl-2-methyl-4-phenylquinolin-1-ium chloride

Tan, Kong Wai and Tiekink, E.R.T. and Kiran, K. and Sarveswari, S. and Vijayakumar, V. (2010) 3-Acetyl-2-methyl-4-phenylquinolin-1-ium chloride. Acta Crystallographica Section E: Structure Reports Online, 66. O2001-U1060. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810027017.

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An N-H...Cl hydrogen bond connects the ions in the title salt, C(18)H(16)NO+center dot Cl-. The quinolin-1-ium residue is almost planar (r.m.s. deviation = 0.020 A) but both the acetyl group [O-C-C-C torsion angle = 62.73 (17)degrees] and adjacent benzene ring [C-C-C-C torsion angle = -104.06 (14)degrees] are twisted out of this plane; the acetyl and benzene substituents are non-parallel [dihedral angle = 66.16 (7)degrees]. The crystal packing is consolidated by C-H...O and C-H...Cl contacts.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Acetyl group; Adjacent benzene ring; Torsion angle; Acetyl; Benzene substituents; Dihedral angle
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 05 Jul 2013 08:27
Last Modified: 30 Jan 2019 08:39
URI: http://eprints.um.edu.my/id/eprint/8024

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