A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol

Tan, Kong Wai and Ng, S.W. and Asiri, A.M. and Khan, S.A. (2010) A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol. Acta Crystallographica Section E: Structure Reports Online, 66 (7). O1826-U789. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810023755.

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In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H atom forms an intramolecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the orthorhombic modification [Liu et al. (2009). Acta Cryst. E65, o738].

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Schiff base; Azomethine double bond; Benzothiazolyl ring; Phenylene ring; Imino group; Monoclinic; Orthorhombic
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 05 Jul 2013 08:36
Last Modified: 30 Jan 2019 08:51
URI: http://eprints.um.edu.my/id/eprint/8021

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